Calculated isotropic Raman spectra from interacting H<sub>2</sub>-rare-gas pairs

TitreCalculated isotropic Raman spectra from interacting H2-rare-gas pairs
Type de publicationArticle de revue
AuteurGustafsson, Magnus , Głaz, Waldemar , Bancewicz, Tadeusz , Godet, Jean-Luc , Maroulis, George , Haskopoulos, Anastasios
EditeurIOP Publishing
TypeArticle scientifique dans une revue sans comité de lecture
Année2014
LangueAnglais
DateDéc.2015
Pagination012027
Volume548
Titre de la revueJournal of Physics: Conference Series
ISSN1742-6588
Mots-cléscollision-induced scattering (CIS), Hydrogen, Raman, rare gases
Résumé en anglais

We report on a theoretical study of the H2–He and H2–Ar pair trace-polarizability and the corresponding isotropic Raman spectra. The conventional quantum mechanical approach for calculations of interaction-induced spectra, which is based on an isotropic interaction potential, is employed. This is compared with a close-coupling approach, which allows for inclusion of the full, anisotropic potential. It is established that the anisotropy of the potential plays a minor role for these spectra. The computed isotropic collision-induced Raman intensity, which is due to dissimilar pairs in H2–He and H2–Ar gas mixtures, is comparable to the intensities due to similar pairs (H2–H2, He–He, and Ar–Ar), which have been studied previously.

URL de la noticehttp://okina.univ-angers.fr/publications/ua14295
DOI10.1088/1742-6596/548/1/012027
Lien vers le document

http://iopscience.iop.org/article/10.1088/1742-6596/548/1/012027/meta

Titre abrégéJ. Phys.: Conf. Ser.