Exact Low-Order Classical Moments in Collision-Induced Bands by Linear Rotors: CO2-CO2

TitreExact Low-Order Classical Moments in Collision-Induced Bands by Linear Rotors: CO2-CO2
Type de publicationArticle de revue
AuteurChrysos, Michel , Kouzov, A.-P., Egorova, N.-I., Rachet, Florent
EditeurAmerican Physical Society
TypeArticle scientifique dans une revue à comité de lecture
Année2008
LangueAnglais
Date2008/04/04
Numéro13
Volume100
Titre de la revuePhysical Review Letters
ISSN0031-9007
Résumé en anglais

Exact and general analytic expressions are reported for the integrated intensity and the width of collision-induced absorption (CIA) and collision-induced scattering (CIS) bands by gases of centrosymmetric linear molecules. These expressions provide significant insight and allow assignment of partial second moments to the degrees of freedom of the colliding molecules. The expressions are applied to ambient CO2, whose collisional spectra are reputed to be useful probes for terrestrial and planetary atmospheres. Compelling evidence of the substantial role of hitherto missing polarization and polarizability mechanisms is provided and is in remarkable agreement with experimental observation. Our findings allow the long-overdue simple interpretation of CIA and CIS by CO2-CO2 without the need to resort to short-range interactions to offset the discrepancies between theory and experiment.

URL de la noticehttp://okina.univ-angers.fr/publications/ua1970
DOI10.1103/PhysRevLett.100.133007
Lien vers le document

http://dx.doi.org/10.1103/PhysRevLett.100.133007