Catechol-appended TTF derivatives

TitreCatechol-appended TTF derivatives
Type de publicationArticle de revue
AuteurEl-Ghayoury, Abdelkrim , Leliège, Antoine, Allain, Magali , Batail, Patrick
TypeArticle scientifique dans une revue à comité de lecture
Année2013
LangueAnglais
Date07/2013
Numéro31
Pagination4015-4018
Volume54
Titre de la revueTetrahedron Letters
ISSN0040-4039
Mots-clésactivation, Catechol, cation, chemistry, conductors, Cyclic voltammetry, Electronic absorption, hydrogen bonds, hydrogen-bond, hydroxyl-groups, recognition, solid-state, Tetrathiafulvalene, transition-metal-complexes
Résumé en anglais

EDT-TTF-CONHCatOH, a catechol-appended TTF derivative, 5 was synthesized through a straightforward strategy. The electronic absorption and the electrochemical investigations as well as molecular orbital calculations for compounds 4 and 5 have been performed. The electrochemical measurements of 5 indicate that it is a suitable candidate for the formation of zwitterionic molecular solids and also two-component radical cation salts. The crystal structure of compound 5 reveals supramolecular dimers assembled via a set of O-H center dot center dot center dot O hydrogen bonds between the catechol and amide units.

URL de la noticehttp://okina.univ-angers.fr/publications/ua2678
DOI10.1016/j.tetlet.2013.05.060