Synthesis and Characterization of Isomerically Pure anti- and syn-Anthradiindole Derivatives

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TitreSynthesis and Characterization of Isomerically Pure anti- and syn-Anthradiindole Derivatives
Type de publicationArticle de revue
AuteurBalandier, Jean-Yves, Henry, N., Arlin, Jean-Baptiste, Sanguinet, Lionel , Lemaur, Vincent, Niebel, Claude, Chattopadhyay, Basab, Kennedy, Alan R, Leriche, Philippe , Blanchard, Philippe , Cornil, Jérôme, Geerts, Yves Henri
EditeurAmerican Chemical Society
TypeArticle scientifique dans une revue à comité de lecture
Année2013
LangueAnglais
Date01/2013
Numéro2
Pagination302-305
Volume15
Titre de la revueOrganic Letters
ISSN1523-7060
Mots-clésacenes, anthradithiophene derivatives, density-functional theory, effect mobility, excitation-energies, field-effect transistors, organic semiconductors, pentacene, photovoltaic cells, thin-film, Transistors
Résumé en anglais

Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by C-13 NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized pi-conjugated systems are evaluated and supported by quantum-chemical calculations.

URL de la noticehttp://okina.univ-angers.fr/publications/ua2722
DOI10.1021/ol303214j