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Titre | Changing gears to neutral in a polymorph of one-dimensional arrays of cogwheel-like pairs of molecular rotors |
Type de publication | Article de revue |
Auteur | Bastien, Guillaume , Lemouchi, Cyprien, Allain, Magali, Wzietek, Pawel, Rodríguez-Fortea, Antonio, Canadell, Enric, Iliopoulos, Konstantinos, Gindre, Denis, Chrysos, Michel , Batail, Patrick |
Editeur | Royal Society of Chemistry |
Type | Article scientifique dans une revue à comité de lecture |
Année | 2014 |
Langue | Anglais |
Date | Jan-01-2014 |
Numéro | 7 |
Pagination | 1241-1244 |
Volume | 16 |
Titre de la revue | CrystEngComm |
Résumé en anglais | We report on a polymorph (2) of an amphidynamic crystal of molecular rods with two helical 1,4-bis(ethynyl)bicyclo[2.2.2]octane rotators where half of the rod-like molecules appear to be shifted with respect to their closest neighbours. This translation takes cogwheel-like pairs of rotators apart in the lattice in such a way that their motion becomes uncorrelated. This property is to be contrasted with the highly correlated motion found to govern the rotators in a recently-published polymorph 1 of the same material. As with polymorph 1, this motion is shown to take place independently of mutations in the handedness of the rotators and of the ‘mutamer’-induced second harmonic generation. |
URL de la notice | http://okina.univ-angers.fr/publications/ua8899 |
DOI | 10.1039/c3ce42054j |
Lien vers le document | |
Titre abrégé | CrystEngComm |